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Stereoselective synthesis of conjugated trans-enynes readily convertible into conjugated cis,trans-dienes and its application to the synthesis of the pheromone bombykol

✍ Scribed by Negishi, Ei-ichi; Lew, George; Yoshida, Takao

Book ID
121447213
Publisher
The Royal Society of Chemistry
Year
1973
Tongue
English
Weight
197 KB
Volume
22
Category
Article
ISSN
0022-4936

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Stereoselective synthesis of conjugated
Stereoselective synthesis of conjugated all-trans-tetraenes. Application to the synthesis of Ξ²-parinaric acid methyl ester
✍ Guy SolladiΓ©; Chakib KalaΓ―; Marc Adamy; FranΓ§oise Colobert πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 174 KB

in this paper is reported the stereoselective synthesis of all-trans-tetraenes by reductive elimination of 1,8-dibenzoate-2,4,6-trienes with sodium amalgam. The method was applied to the syntheses of4E, 6E, BE, 10E-heptatetraene and [~-parinaric acid methyl ester.