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Stereoselective synthesis of (2R, 3S)-syn-2-allyl-3-hydroxy butanoate mediated by an enzymatic system from bakers' yeast

✍ Scribed by Kaoru Nakamura; Takehiko Miyai; Yasushi Kawai; Nobuyoshi Nakajima; Atsuyoshi Ohno

Publisher: Elsevier Science
Year: 1990
Tongue: French
Weight: 126 KB
Volume: 31
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)88752-3

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✦ Synopsis

Reduction of ethyl 2-allyl-3-oxobutanoate by an enzyme fraction obtained from bakers' yeast results in the formation of ethyl (a,%)-sun-2-allyl-3-hydroxybutanoate in an excellent stereoselectivity.

Diastereomerically

as well as enantiomerically pure 2-allyl-3-hydroxy-

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