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Stereoselective synthesis of ethyl (2S,3S)-anti-2-methyl-3-hydroxybutanoate mediated by an Oxidoreductase from Geotrichum candidum

✍ Scribed by Yasushi Kawai; Kousuke Takanobe; Munekazu Tsujimoto; Atsuyoshi Ohno


Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
181 KB
Volume
35
Category
Article
ISSN
0040-4039

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Stereoselective synthesis of (2R, 3S)-sy
✍ Kaoru Nakamura; Takehiko Miyai; Yasushi Kawai; Nobuyoshi Nakajima; Atsuyoshi Ohn πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 126 KB

Reduction of ethyl 2-allyl-3-oxobutanoate by an enzyme fraction obtained from bakers' yeast results in the formation of ethyl (a,%)-sun-2-allyl-3-hydroxybutanoate in an excellent stereoselectivity. ## Diastereomerically as well as enantiomerically pure 2-allyl-3-hydroxy-