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Stereoselective insertion of tetrasubstituted cyclopropylidene into a carbon - hydrogen bond

✍ Scribed by Tatsuya Shono; Ikuzo Nishiguchi; Tawara Komamura; Kahee Fujita


Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
184 KB
Volume
18
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


Stereoselectivity in the insertion of Pt
✍ K.G. Powell; F.J. McQuillin πŸ“‚ Article πŸ“… 1971 πŸ› Elsevier Science 🌐 French βš– 217 KB

A number of strained cycloalkanes have been found to undergo insertion of transition metals, notably Pt(II) and Rh(I), into a carbon-carbon bond (l), and to be sensitive also to cycloalkane -diene isomerisation catalysed by Ag+, and by a range of transition metal

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swmvlry Tert-butylzsocyanide and tert-0ctyZieocyanzde insert znto the carbone-eutftcr bond of actzvated sulfuies 2 yiekizng thzoimidatee S which rearmnge to enamnes g.

First Insertion Reaction of Carbon Monox
✍ Prof. Dr. Ekkehard Lindner; Dipl.-Chem. GΓΌnter von Au πŸ“‚ Article πŸ“… 1980 πŸ› John Wiley and Sons 🌐 English βš– 229 KB

A solution of ( I l i ) (10 g, 19.3 mmol) in 80 ml of anhydrous toluene, which contains 5 ml ethanol, is heated under reflux for 12 h. The solvent is removed and the residue digested with 50 ml pentane. Precipitated Ph3P0 is separated off and the previously unknown 4,5,6,6a-tetrahydro-2( 1 H)-pental