✦ LIBER ✦

First Insertion Reaction of Carbon Monoxide into a Rhenium-Carbon σ-Bond

✍ Scribed by Prof. Dr. Ekkehard Lindner; Dipl.-Chem. Günter von Au

Publisher: John Wiley and Sons
Year: 1980
Tongue: English
Weight: 229 KB
Volume: 19
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.198008241

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✦ Synopsis

A solution of ( I l i ) (10 g, 19.3 mmol) in 80 ml of anhydrous toluene, which contains 5 ml ethanol, is heated under reflux for 12 h. The solvent is removed and the residue digested with 50 ml pentane. Precipitated Ph3P0 is separated off and the previously unknown 4,5,6,6a-tetrahydro-2( 1 H)-pentalenone ( 1 3 ) (1.41 g) isolated by bulb-to-bulb distillation.

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