𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Uncatalyzed insertion reaction of isocyanides into a carbon-sulfur bond

✍ Scribed by G. Morel; E. Marchand; K.H. Nguyem Thi; A. Foucaud

Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
194 KB
Volume
23
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

swmvlry Tert-butylzsocyanide and tert-0ctyZieocyanzde insert znto the carbone-eutftcr bond of actzvated sulfuies 2 yiekizng thzoimidatee S which rearmnge to enamnes g.

πŸ“œ SIMILAR VOLUMES

Isocyanide Insertion into a Uranium-Carb
Isocyanide Insertion into a Uranium-Carbon Double Bond
✍ Prof. Dr. Roger E. Cramer; Dr. K. Panchanatheswaran; Prof. Dr. John W. Gilje πŸ“‚ Article πŸ“… 1984 πŸ› John Wiley and Sons 🌐 English βš– 240 KB πŸ‘ 1 views
First Insertion Reaction of Carbon Monox
First Insertion Reaction of Carbon Monoxide into a Rhenium-Carbon Οƒ-Bond
✍ Prof. Dr. Ekkehard Lindner; Dipl.-Chem. GΓΌnter von Au πŸ“‚ Article πŸ“… 1980 πŸ› John Wiley and Sons 🌐 English βš– 229 KB

A solution of ( I l i ) (10 g, 19.3 mmol) in 80 ml of anhydrous toluene, which contains 5 ml ethanol, is heated under reflux for 12 h. The solvent is removed and the residue digested with 50 ml pentane. Precipitated Ph3P0 is separated off and the previously unknown 4,5,6,6a-tetrahydro-2( 1 H)-pental

Synthetic reactions by complex catalysts
Synthetic reactions by complex catalysts VII : A new insertion reaction of isocyanide into phosphorus-hydrogen bond
✍ Takeo Saegusa; Yoshihiko Ito; Shiro Kobayashi πŸ“‚ Article πŸ“… 1968 πŸ› Elsevier Science 🌐 French βš– 98 KB

We have reported a series of insertion reactions of isocyanides into nitrogen-hydrogen of amine.1) oxygen-hydrogen of alcohol, 2) sulfur-hydrogen of thiol, 3) and silicone-hydrogen of silane4) to produce the corresponding derivatives of N-alkylformimidic acid in high yields.