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Synthetic reactions by complex catalysts VII : A new insertion reaction of isocyanide into phosphorus-hydrogen bond

✍ Scribed by Takeo Saegusa; Yoshihiko Ito; Shiro Kobayashi

Publisher: Elsevier Science
Year: 1968
Tongue: French
Weight: 98 KB
Volume: 9
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)98830-6

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✦ Synopsis

We have reported a series of insertion reactions of isocyanides into nitrogen-hydrogen of amine.1) oxygen-hydrogen of alcohol, 2) sulfur-hydrogen of thiol, 3) and silicone-hydrogen of silane4) to produce the corresponding derivatives of N-alkylformimidic acid in high yields.

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