Stereoselectivity in the insertion of Pt(II) into the carbon-carbon bonds of substituted cyclopropanes
β Scribed by K.G. Powell; F.J. McQuillin
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 217 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
A number of strained cycloalkanes have been found to undergo insertion of transition metals, notably Pt(II) and Rh(I), into a carbon-carbon bond (l), and to be sensitive also to cycloalkane -diene isomerisation catalysed by Ag+, and by a range of transition metal
π SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
Insertion of ethylene into the Tiαmethyl bond in TiH CH q is 2 3 chosen as a model reaction for investigating the performance of a range of contemporary quantum chemical models in polymerization studies. Basis set effects are investigated at the self-consistent-field level, covering HartreeαFock, pu