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Insertion of methylene into the carbon-hydrogen bonds of the C1 to C4 alkanes

โœ Scribed by Marcel L. Halberstadt; John Crump

Publisher
Elsevier Science
Year
1972
Weight
810 KB
Volume
1
Category
Article
ISSN
0047-2670

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A theoretical study of the energetics of
A theoretical study of the energetics of insertion of dicarbon (C2) and vinylidene into methane C๎—ธH bonds
โœ David A. Horner; Larry A. Curtiss; Dieter M. Gruen ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 392 KB

The insertion of dicarbon (C 2) and vinylidene into methane C-H bonds was studied using ab initio molecular orbital theory. The reactions are simple models for thin film diamond growth in which C 2 is the principal growth species. The results of this study suggest that reaction of C 2 with a diamond