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Mechanism of reaction of methylene with the carbon-hydrogen bond: Evidence for direct insertion

โœ Scribed by W. von E. Doering; H. Prinzbach

Publisher
Elsevier Science
Year
1959
Tongue
French
Weight
645 KB
Volume
6
Category
Article
ISSN
0040-4020

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## Abstract Dimethoxycarbene (1a) and methoxy(2,2,2โ€trifluoroethoxy)โ€carbene (1b) were generated in benzene solution by thermolysis of the corresponding 2,2โ€dialkoxyoxadiazolines 7. The carbenes were trapped by intermolecular reaction with a variety of cyclic anhydrides 8. The products 9 are formal