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Stereodynamics of N -Isopropyl- N -methylpropargylamine. Dynamic NMR Studies. Molecular Mechanics Calculations

✍ Scribed by Brown, Jay H.; Bushweller, C. Hackett


Book ID
120666608
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
79 KB
Volume
66
Category
Article
ISSN
0022-3263

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The 1 H and 13 C{ 1 H} NMR spectra of 4-formylcyclohexene in 50% CF 2 Cl 2 -50% CHF 2 Cl decoalesce at very low temperatures and, at 108 K, have sharpened into a major (77%) and a minor (23%) subspectrum. Based on the NMR spectra and molecular mechanics calculations, the major subspectrum is assigne