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Stereodynamics of isopropyldimethylamine. Carbon-13(proton) and proton dynamic NMR studies. Molecular mechanics calculations

โœ Scribed by Brown, Jay H.; Bushweller, C. Hackett


Book ID
127112683
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
785 KB
Volume
114
Category
Article
ISSN
0002-7863

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H and 13C NMR chemical shifts of a series of 1 -substituted pyridinium salts were measured in dimethyl sulfoxide. The effect of the quaternary pyridinium ring on the resonance of the methylene group of the substituent is reported. Increments of 6'H = 3.89 f 0.1 6 ppm and 6' 3C = 47.5 f 3.7 ppm are e