Stereodynamics of N -Allyl- N -methyl-2-aminopropane. 1 H and 13 C{ 1 H} DNMR Studies. Molecular Mechanics Calculations
β Scribed by Brown, Jay H.; Bushweller, C. Hackett
- Book ID
- 126014477
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 202 KB
- Volume
- 101
- Category
- Article
- ISSN
- 1089-5639
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The 13C-{1H}-n.m.r. spectra (acidic D,O, pD -1) of N-methyl-l-deoxynojirimycin (1,5-dideoxy-1,5-methyliminium-D-glucitol), an inhibitor of processing cx-D-glucosidases involved in glycopeptide biosynthesis, showed two isomers (-11:l ratio) differing in the stereochemistry of the N+DCH3 group. Assig