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Stereochemistry and mechanism of the hydrogenation of substituted cyclopentenes

โœ Scribed by S. Mitsui; Y. Senda; H. Suzuki; S. Sekiguchi; Y. Kumagai

Book ID
108374150
Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
493 KB
Volume
29
Category
Article
ISSN
0040-4020

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๐Ÿ“œ SIMILAR VOLUMES

Stereochemistry and mechanism of catalyt
Stereochemistry and mechanism of catalytic hydrogenation of substituted methylenecyclohexanes
โœ S. Mitsui; K. Gohke; H. Saito; A. Nanbu; Y. Senda ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 598 KB

Substituted alkyhnethylenecyclohexanes were hydrogenated over several transition metal catalysts. The ratios of the epimeric products were almost unity over freshly prepared Raney Ni but the axial Me counterparts were favoured over aged catalyst. The axial Me products were also preferred on Pt or Rh