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Stereochemistry and the mechanism of the hydrogenation of substituted cyclopentanones and methylenecyclopentanes

✍ Scribed by S. Mitsui; H. Saito; S. Sekiguchi; Y. Kumagai; Y. Senda

Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
573 KB
Volume
28
Category
Article
ISSN
0040-4020

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πŸ“œ SIMILAR VOLUMES

Stereochemistry and mechanism of catalyt
Stereochemistry and mechanism of catalytic hydrogenation of substituted methylenecyclohexanes
✍ S. Mitsui; K. Gohke; H. Saito; A. Nanbu; Y. Senda πŸ“‚ Article πŸ“… 1973 πŸ› Elsevier Science 🌐 French βš– 598 KB

Substituted alkyhnethylenecyclohexanes were hydrogenated over several transition metal catalysts. The ratios of the epimeric products were almost unity over freshly prepared Raney Ni but the axial Me counterparts were favoured over aged catalyst. The axial Me products were also preferred on Pt or Rh