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Stereochemistry and mechanism of the catalytic hydrogenation of dimethylcyclohexenes

โœ Scribed by S. Mitsui; S. Imaizumi; A. Nanbu; Y. Senda

Book ID
113174954
Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
285 KB
Volume
36
Category
Article
ISSN
0021-9517

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๐Ÿ“œ SIMILAR VOLUMES

Stereochemistry and mechanism of catalyt
Stereochemistry and mechanism of catalytic hydrogenation of substituted methylenecyclohexanes
โœ S. Mitsui; K. Gohke; H. Saito; A. Nanbu; Y. Senda ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 598 KB

Substituted alkyhnethylenecyclohexanes were hydrogenated over several transition metal catalysts. The ratios of the epimeric products were almost unity over freshly prepared Raney Ni but the axial Me counterparts were favoured over aged catalyst. The axial Me products were also preferred on Pt or Rh