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Stereochemical fate of an asymmetric migrating group in the pinacol rearrangement

✍ Scribed by Beggs, J. J.; Meyers, M. B.


Book ID
121379424
Publisher
Royal Society of Chemistry
Year
1970
Weight
671 KB
Category
Article
ISSN
0045-6470

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Completely stereospecific 1,2-migration
✍ Gen-ichi Tsuchihashi; Katsuhiko Tomooka; Keisuke Suzuki πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 French βš– 257 KB

## swnmary: Completely stereospecific 1,2-migration of alkyl groups was achieved in Et2AlCL- prowted pinacoZ-type rearrangement of chiral B-mesyZoxy alcohols to give optically pure aalkyl ketones including both enantiomers of 4-methyl-3-hexanone, an alarm pheromone of ant.