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Completely stereospecific 1,2-migration of alkyl groups in Et2AlCl promoted pinacol-type rearrangement

✍ Scribed by Gen-ichi Tsuchihashi; Katsuhiko Tomooka; Keisuke Suzuki

Book ID: 104233776
Publisher: Elsevier Science
Year: 1984
Tongue: French
Weight: 257 KB
Volume: 25
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)81409-x

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✦ Synopsis

swnmary:

Completely stereospecific 1,2-migration of alkyl groups was achieved in Et2AlCL- prowted pinacoZ-type rearrangement of chiral B-mesyZoxy alcohols to give optically pure aalkyl ketones including both enantiomers of 4-methyl-3-hexanone, an alarm pheromone of ant.

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