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Rearrangement of Alkyl Groups. Kinetic and Tracer Studies in the Pinacol Rearrangement 1

✍ Scribed by Stiles, Martin; Mayer, Raymond P.

Book ID
120487124
Publisher
American Chemical Society
Year
1959
Tongue
English
Weight
938 KB
Volume
81
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Completely stereospecific 1,2-migration
Completely stereospecific 1,2-migration of alkyl groups in Et2AlCl promoted pinacol-type rearrangement
✍ Gen-ichi Tsuchihashi; Katsuhiko Tomooka; Keisuke Suzuki πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 French βš– 257 KB

## swnmary: Completely stereospecific 1,2-migration of alkyl groups was achieved in Et2AlCL- prowted pinacoZ-type rearrangement of chiral B-mesyZoxy alcohols to give optically pure aalkyl ketones including both enantiomers of 4-methyl-3-hexanone, an alarm pheromone of ant.