Stereo- and regio-controlled aldol synthesis
β Scribed by Isao Kuwajima; Masahiro Kato; Akio Mori
- Book ID
- 104225587
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- French
- Weight
- 217 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0040-4039
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## Abstract [24,30β^14^C]β(3S)β2,3βEpoxysqualene and its racemate were synthesized by two convenient routes. The products have the label in a metabolicallyβnonlabile position relative to the demethylation of lanosterol to cholesterol.
Cycloheptene is readily converted to the cationic cycloheptadiene-Mo(CO)2CP complex, which reacts with a range of nucleophiles; hydride abstraction from the product 7allyl-Mo(CO)2C p complexes give substituted cyeloheptadiene complexes which react with a second nueleophile stereospeeifically, and de