✦ LIBER ✦

Stereo- and regio-controlled functionalization of cycloheptene using organomolybdenum chemistry

✍ Scribed by Anthony J. Pearson; Md. Nazrul I. Khan

Book ID: 104229209
Publisher: Elsevier Science
Year: 1985
Tongue: French
Weight: 165 KB
Volume: 26
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)99057-9

No coin nor oath required. For personal study only.

✦ Synopsis

Cycloheptene is readily converted to the cationic cycloheptadiene-Mo(CO)2CP complex, which reacts with a range of nucleophiles; hydride abstraction from the product 7allyl-Mo(CO)2C p complexes give substituted cyeloheptadiene complexes which react with a second nueleophile stereospeeifically, and decomplexation of the ~-allyl complexes gives substituted cycloheptene derivatives with defined relative stereochemistry.

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