Static and dynamical solvent effects on electron transfer rates
โ Scribed by M. Tachiya
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 336 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0969-806X
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๐ SIMILAR VOLUMES
Isomerization of the cationic complex of the type Coen?Xi (X-= singly charged anionic ligand) in basic solution proceeds through ion-pair formation [l], The, study of isomerization of the present anionic complex was undertaken as with this complex, ion-pair formation is untenable and isomerization m
We analyse outer-sphere electron transfer (ET) in a dielectric medium, which is characterised by a continuous distribution of dielectric relaxation times. An explicit expression for the averaged ET rate is derived in the particular case of the Davidson-Cole dielectric susceptibility function. A quan