Solvent and counter-ion effects on intramolecular electron transfer rates of an organic mixed-valence compound
β Scribed by Haruko Hosoi; Yuichi Masuda
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 230 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0167-7322
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π SIMILAR VOLUMES
Electron transfer in chemical''] and biological [2] systems has received considerable attention in the last few years. Recent studies of electron transfer in mixed-valence biferrocenium complexes 1-6 revealed that the environment surrounding a cation is perhaps the most important factor in determini
Pseudo first-order rate constants (kohl) for methanolysis of ionized phenyl salicylate (PS-) show a decrease of 3-5-fold with increase in CH,CN content from 2 to 60 or 70% (v/v) in mixed aqueous solvents containing 0.01 mol dm-3 LiOH and a constant content of CH30H. At 0.01 moldm-' KOH, the rate con