Femtosecond intermolecular electron (ET) transfer dynamics were studied by time-resolved fluorescence up-conversion technique in contact systems of oxazine dyes in electron-donating solvents. Clearly non-exponential ET time dependence was observed in aniline and explained by the effects of both solv
Solvent and nuclear dynamic effects on intermolecular electron transfer
โ Scribed by Keitaro Yoshihara; Yutaka Nagasawa; Arkadiy Yartsev; Alan E. Johnson; Keisuke Tominaga
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 624 KB
- Volume
- 65-66
- Category
- Article
- ISSN
- 0167-7322
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๐ SIMILAR VOLUMES
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We analyse outer-sphere electron transfer (ET) in a dielectric medium, which is characterised by a continuous distribution of dielectric relaxation times. An explicit expression for the averaged ET rate is derived in the particular case of the Davidson-Cole dielectric susceptibility function. A quan