✦ LIBER ✦

The effect of solvent relaxation dynamics on outer-sphere electron transfer

✍ Scribed by Ilya Rips; Joshua Jortner

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 391 KB
Volume: 133
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(87)87092-6

No coin nor oath required. For personal study only.

✦ Synopsis

We analyse outer-sphere electron transfer (ET) in a dielectric medium, which is characterised by a continuous distribution of dielectric relaxation times. An explicit expression for the averaged ET rate is derived in the particular case of the Davidson-Cole dielectric susceptibility function. A quantitative account of recent experimental data for ET in the Ru(phen#+ methylviologen*+ system in glycerol is provided.

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