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The effect of quantum vibrations on electrochemical outer sphere redox reactions

✍ Scribed by W. Schmickler

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
715 KB
Volume
21
Category
Article
ISSN
0013-4686

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We analyse outer-sphere electron transfer (ET) in a dielectric medium, which is characterised by a continuous distribution of dielectric relaxation times. An explicit expression for the averaged ET rate is derived in the particular case of the Davidson-Cole dielectric susceptibility function. A quan