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Stability and Thermal Rearrangement of ( E , E )-1,3-Cycloheptadiene and trans -Bicyclo[3.2.0]hept-6-ene

โœ Scribed by Qin, Changyong; Davis, Steven R.; Zhao, Zhendong; Magers, David H.


Book ID
118135803
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
160 KB
Volume
110
Category
Article
ISSN
1089-5639

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Derivatives of trans-bicyclo[4.1.0]hept-3-ene with chlorine and bromine substituents the 7 position were synthesized and their thermal rearrangements were examined. Thermolysis of the dichloride leads to the formation of the cis-fused isomer, while heating the dibromide results in ring-expanded prod