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Transition-metal complexes of bicyclo[3.1.0]hex-5-ene and bicyclo[4.1.0]hept-6-ene

✍ Scribed by Yin, Jianguo; Jones, W. M.


Book ID
126506554
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
273 KB
Volume
12
Category
Article
ISSN
0276-7333

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Rearrangement of a Bicyclo[3.2.0]hept-2-
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## Abstract The chemistry of the highly substituted cyclobutanone derivative 2, which is easily accessible from 1, is dominated by the steric hindrance caused by the substitutents: Reduction with hydride reagents and nucleophilic additions with methyllithium are less stereoselective than correspond