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ChemInform Abstract: Rearrangement of a Bicyclo(3.2.0)hept-2-ene to a Bicyclo(4.1.0)hept-4- ene.

✍ Scribed by U. BEHRENDT; B. GABOR; R. MYNOTT; H. BUTENSCHOEN

Book ID
112038206
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
27
Category
Article
ISSN
0931-7597

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Rearrangement of a Bicyclo[3.2.0]hept-2-
Rearrangement of a Bicyclo[3.2.0]hept-2-ene to a Bicyclo[4.1.0]hept-4-ene
✍ Behrendt, Uwe ;Gabor, Barbara ;Mynott, Richard ;ButenschΓΆn, Holger πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 996 KB

## Abstract The chemistry of the highly substituted cyclobutanone derivative 2, which is easily accessible from 1, is dominated by the steric hindrance caused by the substitutents: Reduction with hydride reagents and nucleophilic additions with methyllithium are less stereoselective than correspond