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Synthesis and thermal isomerization of trans-bicyclo[4.1.0]hept-3-ene

✍ Scribed by Gassman, Paul G.; Bonser, Steven M.

Book ID: 127130056
Publisher: American Chemical Society
Year: 1983
Tongue: English
Weight: 385 KB
Volume: 105
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00341a082

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## Abstract The chemistry of the highly substituted cyclobutanone derivative 2, which is easily accessible from 1, is dominated by the steric hindrance caused by the substitutents: Reduction with hydride reagents and nucleophilic additions with methyllithium are less stereoselective than correspond