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Spectroscopic and electrochemical studies on ruthenium(II) complexes containing diazadiimine ligands

✍ Scribed by Noboru Kitamura; Yuji Kawanishi; Shigeo Tazuke

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 321 KB
Volume: 97
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)87193-0

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✦ Synopsis

Newly prepared ruthenium(I1) complexes, RuL3, containins 3,3'-bipyridazine. 6,6'-dimethy13,4'-bipyrimidinc. and 4-methyl-2_(2'-pyridyl)pyrimidine as li_eands (L) were studied by absorption and emission spectroscopy as well as by cyclic voltammetry. The metal-to-ligand charge-transfer absorption spectra and the photocatalytic ability of these KuL3 complexes were discussed on the basis of the redor properties of L and RuL3.

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