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Synthesis, Crystal Structures and NMR Spectroscopic Studies on Ruthenium Complexes with Phosphanylacetal and Phosphanylthioacetal Ligands

✍ Scribed by Simon R. Bayly; Andrew R. Cowley; Jonathan R. Dilworth; Caroline V. Ward


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
594 KB
Volume
2009
Category
Article
ISSN
1434-1948

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## Abstract Reaction of WX~6~ (X = Cl or Br) with O(SiMe~3~)~2~ in CH~2~Cl~2~, followed by addition of MeCN and a further equivalent of O(SiMe~3~)~2~ in CH~2~Cl~2~ gives [WO~2~X~2~(MeCN)~2~] in situ, which subsequently react with the dithioethers MeS(CH~2~)~2~SMe, __i__PrS(CH~2~)~2~S__i__Pr or 1,4‐