Synthetic and electrochemical studies on alkynyl complexes of iron and ruthenium
β Scribed by Caroline Bitcon; Mark W. Whiteley
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 585 KB
- Volume
- 336
- Category
- Article
- ISSN
- 0022-328X
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Newly prepared ruthenium(I1) complexes, RuL3, containins 3,3'-bipyridazine. 6,6'-dimethy13,4'-bipyrimidinc. and 4-methyl-2\_(2'-pyridyl)pyrimidine as li\_eands (L) were studied by absorption and emission spectroscopy as well as by cyclic voltammetry. The metal-to-ligand charge-transfer absorption sp
The reactivity of aminodihaloboranes R 2 NBX 2 (R = Me, be isolated from these mixtures as pure materials. In addition the novel boryl and borylene ruthenium complexes [(Ξ· 5 -SiMe 3 ; X = Cl, Br) towards transition metal complexes of the type Na[(Ξ· 5 -C 5 RΠ 5 )M(CO) 2 )] (M = Fe, Ru; RΠ = H, Me) wa