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Cyclopentadienyl Ruthenium(II) Complexes with Bridging Alkynylphosphine Ligands: Synthesis and Electrochemical Studies

✍ Scribed by Barbara Di Credico; Fabrizia Fabrizi de Biani; Luca Gonsalvi; Annalisa Guerri; Andrea Ienco; Franco Laschi; Maurizio Peruzzini; Gianna Reginato; Andrea Rossin; Piero Zanello


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
484 KB
Volume
15
Category
Article
ISSN
0947-6539

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The novel tridentate 2,2':6',2''-terpyridine ligand (1) in which the metalbinding domain is directly attached to a methanofullerene C 60 unit was incorporated into ruthenium-based diads and triads that may undergo photoinduced charge separation. In this paper, the new complexes are compared with mor