Synthesis and Magnetic Studies of Copper (II)-Manganese (II) Heterobinuclear Complexes with an Oxamido Bridge
β Scribed by Yan-Tuan Li; Xue-Dong Zhu; Cui-Wei Yan; Dai-Zheng Liao
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 473 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0256-7660
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The synthesis, characterization and crystal structures of substituted imidazolate bridged binuclear copper(II) complexes, [Cu 2 (dien) 2 (L)](ClO 4 ) 3 , where dien Ο diethylenetriamine, L Ο imidazolate (im Οͺ ) (1), 2-methylimidazolate (mim Οͺ ) (2) and benzimidazolate (bim Οͺ ) (3), are reported. The
mation about designing and synthesizing molecule-based magnets\* and investigating the spin-exchange mechanism between panmagnetic meta~ ions. ' here were Felatively few studies dealing with hetenmetal complexes containing d-transition metal ions and lanthanide(III) ions (socalled d-f hetemuclear co