Specificity in photochemical cycloadditions
β Scribed by Mordecai B. Rubin; Donald Glover; Richard G. Parker
- Book ID
- 104223572
- Publisher
- Elsevier Science
- Year
- 1964
- Tongue
- French
- Weight
- 217 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Photocycloaddittons of 2-trimethylsilylcyclopentenone to isobutylene, methylene cyclohexane, and isopropenyl acetate using stannous chloride-filtered light affords regiospecifically the head-to-tail cycloadducts. Desilylation of these compounds affords the respective cycloadducts of cyclopentenone i
Diarylthioketones 1,2 , thiophosgene3, and thione carbonates 4 react with substituted alkenes under photochemical conditions to give thietanes and in some cases, 1,4-dithianes. It is known that thioparabanates, A, undergo photoreduction in ethanolic solution5. However, the formation of a small amoun