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Photochemical 8 + 2 cycloadditions of tropone

✍ Scribed by Cantrell, Thomas S.


Book ID
127274706
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
262 KB
Volume
93
Category
Article
ISSN
0002-7863

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Photochemical transformation of tropone
✍ T. Tezuka; A. Yanagi; T. Mukai πŸ“‚ Article πŸ“… 1970 πŸ› Elsevier Science 🌐 French βš– 245 KB

We wish to report a novel pho~o~hemical transformation of trapone phenylhydrazone (I) to 2-phenylindazole (II) and a related chemical reaction of I with lead tetraacetate.

Regioselective photochemical cycloadditi
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Photocycloaddittons of 2-trimethylsilylcyclopentenone to isobutylene, methylene cyclohexane, and isopropenyl acetate using stannous chloride-filtered light affords regiospecifically the head-to-tail cycloadducts. Desilylation of these compounds affords the respective cycloadducts of cyclopentenone i