𝔖 Bobbio Scriptorium
✦   LIBER   ✦

PHOTOCHEMICAL CYCLOADDITIONS OF ORGANIC COMPOUNDS

✍ Scribed by CARLOS RIVAS; ELISEO PAYO; JOAQUÍN MANTECÓN; LUIS CORTÉS


Book ID
114891346
Publisher
John Wiley and Sons
Year
1968
Tongue
English
Weight
237 KB
Volume
7
Category
Article
ISSN
0031-8655

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Photocycloaddittons of 2-trimethylsilylcyclopentenone to isobutylene, methylene cyclohexane, and isopropenyl acetate using stannous chloride-filtered light affords regiospecifically the head-to-tail cycloadducts. Desilylation of these compounds affords the respective cycloadducts of cyclopentenone i

Photochemical cycloadditions of thiopara
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Diarylthioketones 1,2 , thiophosgene3, and thione carbonates 4 react with substituted alkenes under photochemical conditions to give thietanes and in some cases, 1,4-dithianes. It is known that thioparabanates, A, undergo photoreduction in ethanolic solution5. However, the formation of a small amoun