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Specific oxidation of methionine to methionine sulfoxide by dimethyl sulfoxide

✍ Scribed by Lipton, Samuel H.; Bodwell, C. E.


Book ID
121278453
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
772 KB
Volume
24
Category
Article
ISSN
0021-8561

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πŸ“œ SIMILAR VOLUMES


Oxidation of methionine to methionine su
✍ Regula Joppich-Kuhn; Jeffrey A. Corkill; Roger W. Giese πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 English βš– 378 KB

In addition to cleaving the peptide bond in N-pentafluorobenzoyl-methionyl-glycine, cyanogen bromide can also oxidize this peptide to the corresponding sulfoxide, particularly at a higher pH. The yields of this sulfoxide are 1, 8, 64, and 97% when the reaction conditions are 70% formic acid, 0.1 M h