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Chloroauric acid as oxidant. Stereospecific oxidation of methionine to methionine sulfoxide

✍ Scribed by Natile, Giovanni.; Bordignon, Emilio.; Cattalini, Lucio.

Book ID
120525608
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
460 KB
Volume
15
Category
Article
ISSN
0020-1669

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πŸ“œ SIMILAR VOLUMES

Oxidation of methionine to methionine su
Oxidation of methionine to methionine sulfoxide as a side reaction of cyanogen bromide cleavage
✍ Regula Joppich-Kuhn; Jeffrey A. Corkill; Roger W. Giese πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 English βš– 378 KB

In addition to cleaving the peptide bond in N-pentafluorobenzoyl-methionyl-glycine, cyanogen bromide can also oxidize this peptide to the corresponding sulfoxide, particularly at a higher pH. The yields of this sulfoxide are 1, 8, 64, and 97% when the reaction conditions are 70% formic acid, 0.1 M h