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The Quantitative Oxidation of Methionine to Methionine Sulfoxide by Peroxynitrite

โœ Scribed by Daniel Perrin; Willem H. Koppenol

Book ID
115568194
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
98 KB
Volume
377
Category
Article
ISSN
0003-9861

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๐Ÿ“œ SIMILAR VOLUMES

Oxidation of methionine to methionine su
Oxidation of methionine to methionine sulfoxide as a side reaction of cyanogen bromide cleavage
โœ Regula Joppich-Kuhn; Jeffrey A. Corkill; Roger W. Giese ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 378 KB

In addition to cleaving the peptide bond in N-pentafluorobenzoyl-methionyl-glycine, cyanogen bromide can also oxidize this peptide to the corresponding sulfoxide, particularly at a higher pH. The yields of this sulfoxide are 1, 8, 64, and 97% when the reaction conditions are 70% formic acid, 0.1 M h