Special Series: Advances in the investigation of the structure-function relationship in nucleic acids and their assemblies
โ Scribed by Dan Fabris
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2009
- Tongue
- English
- Weight
- 34 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0006-3525
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## Abstract A postsynthetic, onโcolumn Sonogashira reaction was applied on DNA molecules modified by 2โ or 4โiodophenylmethylglycerol in the middle of the sequence, to give the corresponding __ortho__โ and __para__โtwisted intercalating nucleic acids (TINA) with 1โ, 2โ, and 4โethynylpyrene residues
Ten di-n-butyltin (IV) carboxylates [("Bu$n-OCOR'),O/, and nBu$n(OCOR'), (R' = CC13 CHCI, CH2Cl, PhCH = CH, and 2,2,3,3-tetramethylcyclopropyl) were synthesized and characterized by IR, 'H, I3C, Il9Sn NMR spectroscopy and elemental analysis. Together with other series of organotin(IV) carboxylates,