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Solvothermal Syntheses and Crystal Structures of Rare Earth Thioantimonates [Y(en)4]SbS4·0.5en and [Tm(en)4]SbS4·0.5en

✍ Scribed by Jing-jing Liang; Jing Zhao; Qin-yan Jin; Ding-xian Jia; Yong Zhang; Jian-sheng Gu


Book ID
106404560
Publisher
Springer
Year
2010
Tongue
English
Weight
312 KB
Volume
40
Category
Article
ISSN
1572-8854

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Solvothermal syntheses and characterizat
✍ Ding-Xian Jia; Jie Deng; Qian-Xin Zhao; Yong Zhang 📂 Article 📅 2007 🏛 Elsevier Science 🌐 English ⚖ 309 KB

Two new lanthanide thioantimonates, [Pr(en) 3 (H 2 O)(l 2 -SbS 4 )] and [Gd(en) 4 ]SbS 4 AE0.5en (en = ethylenediamine), were synthesized using the solvothermal method by reacting LnCl 3 , Sb and S in en at 160 °C. The crystal structure of 1 consists of a one-dimensional [Pr(en) 3 (H 2 O)(l 2 -SbS 4