Solvothermal syntheses and characterizat
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Ding-Xian Jia; Jie Deng; Qian-Xin Zhao; Yong Zhang
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Article
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2007
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Elsevier Science
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English
⚖ 309 KB
Two new lanthanide thioantimonates, [Pr(en) 3 (H 2 O)(l 2 -SbS 4 )] and [Gd(en) 4 ]SbS 4 AE0.5en (en = ethylenediamine), were synthesized using the solvothermal method by reacting LnCl 3 , Sb and S in en at 160 °C. The crystal structure of 1 consists of a one-dimensional [Pr(en) 3 (H 2 O)(l 2 -SbS 4