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ChemInform Abstract: Solvothermal Syntheses, and Characterization of [Ln(en)4(SbSe4)] (Ln: Ce, Pr) and [Ln(en)4]SbSe4×0.5en (Ln: Eu, Gd, Er, Tm, Tb): The Effect of Lanthanide Contraction of the Crystal Structures of Lanthanide Selenidoantimonates(V).

✍ Scribed by Dingxian Jia; Aimei Zhu; Qinyan Jin; Yong Zhang; Wenqing Jiang


Publisher
John Wiley and Sons
Year
2008
Weight
27 KB
Volume
39
Category
Article
ISSN
0931-7597

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Solvothermal Synthesis, Crystal Structur
✍ Ding-Xian Jia; Qian-Xin Zhao; Yong Zhang; Jie Dai; Jian Zhou 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 150 KB 👁 1 views

## Abstract Three new lanthanide selenidoantimonates [Ln(en)~4~(SbSe~4~)] [Ln = La (1), Nd (2)] and [Sm(en)~4~]SbSe~4~·0.5en (3) (en = ethylenediamine) were first synthesized by treating LnCl~3~, Sb, and Se in a stoichiometric ratio with en under mild solvothermal conditions. Compounds 1 and 2 are