Solvothermal Synthesis, Crystal Structures, and Properties of New Selenidoantimonates [Ln(en)4(SbSe4)] (Ln: La, Nd) and [Sm(en)4]SbSe4×0.5en: The First Example of an SbSe43- Anion Acting as a Ligand to a Lanthanide Complex.
✍ Scribed by Ding-Xian Jia; Qian-Xin Zhao; Yong Zhang; Jie Dai; Jian Zhou
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 16 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Three new lanthanide selenidoantimonates [Ln(en)~4~(SbSe~4~)] [Ln = La (1), Nd (2)] and [Sm(en)~4~]SbSe~4~·0.5en (3) (en = ethylenediamine) were first synthesized by treating LnCl~3~, Sb, and Se in a stoichiometric ratio with en under mild solvothermal conditions. Compounds 1 and 2 are
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