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Solvothermal syntheses, and characterization of [Ln(en)4(SbSe4)] (Ln=Ce, Pr) and [Ln(en)4]SbSe4·0.5en (Ln=Eu, Gd, Er, Tm, Yb): The effect of lanthanide contraction on the crystal structures of lanthanide selenidoantimonates(V)

✍ Scribed by Dingxian Jia; Aimei Zhu; Qinyan Jin; Yong Zhang; Wenqing Jiang


Book ID
108195620
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
446 KB
Volume
181
Category
Article
ISSN
0022-4596

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Solvothermal Synthesis, Crystal Structur
✍ Ding-Xian Jia; Qian-Xin Zhao; Yong Zhang; Jie Dai; Jian Zhou 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 150 KB 👁 1 views

## Abstract Three new lanthanide selenidoantimonates [Ln(en)~4~(SbSe~4~)] [Ln = La (1), Nd (2)] and [Sm(en)~4~]SbSe~4~·0.5en (3) (en = ethylenediamine) were first synthesized by treating LnCl~3~, Sb, and Se in a stoichiometric ratio with en under mild solvothermal conditions. Compounds 1 and 2 are