𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Solvent effects on metal to ligand charge transfer excitations

✍ Scribed by N.S. Hush; J.R. Reimers

Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
257 KB
Volume
177
Category
Article
ISSN
0010-8545

No coin nor oath required. For personal study only.

✦ Synopsis

The method for calculating solvent shifts on metal to ligand charge transfer (MLCT) and other electronic absorption bands involving charge transfer (e.g. ligand to metal and organic charge transfer) developed by Zeng, Hush and Reimers, henceforth named ZHR-SS, is reviewed. Also included are simple models for MLCT processes in mono-and di-metal complexes and a description of key aspects of modern electroabsorption spectroscopic techniques used to study MLCT transitions. The rationale behind ZHR-SS is summarized, as

πŸ“œ SIMILAR VOLUMES

Photochemistry induced by metal-to-ligan
Photochemistry induced by metal-to-ligand charge transfer excitation
✍ Arnd Vogler; Horst Kunkely πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 English βš– 103 KB

The photoreactivity of coordination compounds in a MLCT excited state can be attributed to the nature of the oxidized metal and/or the reduced ligand. The general features of such photoreactions have been recently reviewed (A. Vogler, H. Kunkely, Coord. Chem. Rev. 177 (1998) 81). The present report

Metalβ€”Molecule charge-transfer excitatio
Metalβ€”Molecule charge-transfer excitations on silver films
✍ D. Schmeisser; J.E. Demuth; Ph. Avouris πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 English βš– 267 KB

Rcccivcd 15 Ocrobcr 198 I, I" ilml iornl7 January 1982 Ekc~ron cnerg loss spccw oiCO.02. C?H~,ald CsHjN ddsorbed on srlvcr fdms evaporated at 7-O E show rn add!-Iron to tbr inrram!Aecular transwons. new bands beluccn 1 and 1 eV. Thcsc are Idcnrfied 3s metal-molecule clwge-IraNicr evararions loczlizc

Solvent effects on intervalence charge t
Solvent effects on intervalence charge transfer
✍ Roderick D. Cannon πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 English βš– 476 KB

The solvent reorganisation energies associated with charge transfer spectroscopic transitions in molecules of ellipsoidal shape are calculated by a novel adaptation of the Kirkwood-Westheimer equations, and compared with experimental data for (i) mixed-valence ruthenium(II)-ruthenium(III) complexes,