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Solvent effects on intervalence charge transfer

✍ Scribed by Roderick D. Cannon

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
476 KB
Volume
49
Category
Article
ISSN
0009-2614

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✦ Synopsis

The solvent reorganisation energies associated with charge transfer spectroscopic transitions in molecules of ellipsoidal shape are calculated by a novel adaptation of the Kirkwood-Westheimer equations, and compared with experimental data for (i) mixed-valence ruthenium(II)-ruthenium(III) complexes, and (ii) outer-sphere ruthenium(W-halide complexes.

πŸ“œ SIMILAR VOLUMES

A model for solvent and pressure effects
A model for solvent and pressure effects on charge transfer absorption bands
✍ Issam Jano πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 English βš– 432 KB

A model is proposed for interpreting the effects of solvent and pressure on charge transfer absorption bands. The model is based on considering the complex as a super molecule in a homogeneous medium with a dielectric wm&mt D. Application to some iodine complexes is discussed.