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Photochemistry induced by metal-to-ligand charge transfer excitation

✍ Scribed by Arnd Vogler; Horst Kunkely

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
103 KB
Volume
208
Category
Article
ISSN
0010-8545

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✦ Synopsis

The photoreactivity of coordination compounds in a MLCT excited state can be attributed to the nature of the oxidized metal and/or the reduced ligand. The general features of such photoreactions have been recently reviewed (A. Vogler, H. Kunkely, Coord. Chem. Rev. 177 (1998) 81). The present report contains an update of our observations on this subject. In particular, the spectroscopy and photochemistry of the following complexes is discussed: [Re I (CO)

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