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Switching between Ligand-to-Ligand Charge-Transfer, Intraligand Charge-Transfer, and Metal-to-Ligand Charge-Transfer Excited States in Platinum(II) Terpyridyl Acetylide Complexes Induced by pH Change and Metal Ions

✍ Scribed by Xue Han; Li-Zhu Wu; Gang Si; Jie Pan; Qing-Zheng Yang; Li-Ping Zhang; Chen-Ho Tung

Publisher: John Wiley and Sons
Year: 2007
Tongue: English
Weight: 203 KB
Volume: 13
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.200600769

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## Abstract The __trans‐cis__ isomerization of the styrylpyridine carbon–carbon double bond induced by visible light irradiation in __fac__‐[Re(CO)~3~(bpy)(stpy)]^+^ (bp__y__ = 2,2′‐bipyridine; stpy = __t__‐4‐styrylpyridine) has been investigated by means of quantum‐chemical methods. The structures